PTHH: \(C_2H_5OH+3O_2\xrightarrow[]{t^o}2CO_2+3H_2O_{ }\)

           \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\)

a) Ta có: \(n_{CaCO_3}=\dfrac{160}{100}=1,6\left(mol\right)=n_{CO_2}\) \(\Rightarrow n_{O_2}=2,4\left(mol\right)\)

\(\Rightarrow V_{kk}=\dfrac{2,4\cdot22,4}{20\%}=268,8\left(l\right)\)

b) Theo PTHH: \(n_{C_2H_5OH}=\dfrac{1}{2}n_{CO_2}=0,8\left(mol\right)\)

\(\Rightarrow a=C\%_{C_2H_5OH}=\dfrac{0,8\cdot46}{50\cdot0,8}\cdot100\%=92\%=92^o\)

A tác dụng với NaHCO₃ cho khí CO2 → A: axit CH₃COOH

BTKL: m + m_O2 = m_CO2 + m_H2O => m = 1,8

=> n_CH3COOH = 0,03

CH₃COOH + C₂H₅OH → CH₃COOC₂H₅ + H₂O

0,03                 0,02                 0,0125

=> H = 62,5%

\(n_{C_2H_5OH}=\dfrac{9,2}{46}=0,2\left(mol\right)\)

\(C_2H_5OH+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

0,2              0,6         0,4      0,4 

\(a,V_{O_2}=0,6.22,4=13,44\left(l\right)\)

\(V_{kk}=13,44.5=67,2\left(l\right)\)

b, \(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\)

    0,4                               0,4 

\(m_{CaCO_3}=0,4.100=40\left(g\right)\)

\(m_{CaCO_3tt}=40.95\%=38\left(g\right)\)

a, \(n_{C_2H_4}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

PT: \(C_2H_4+3O_2\underrightarrow{t^o}2CO_2+2H_2O\)

\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)

Theo PT: \(n_{CaCO_3}=n_{CO_2}=2n_{C_2H_4}=0,1\left(mol\right)\)

\(\Rightarrow m_{CaCO_3}=0,1.100=10\left(g\right)\)

b, Theo PT: \(n_{O_2}=3n_{C_2H_4}=0,15\left(mol\right)\Rightarrow V_{O_2}=0,15.22,4=3,36\left(l\right)\)

\(\Rightarrow V_{kk}=\dfrac{V_{O_2}}{20\%}=16,8\left(l\right)\)

C2H4+3O2-to>2CO2+2H2O

0,25----0,75------0,5

CO2+Ca(OH)2->CaCO3+H2O

0,5-----------------------0,5

n C2H4=0,25 mol

=>Vkk=0,75.22,4.5=84l

b)m CaCO3=0,5.100=50g

\(n_{C_2H_4}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\\ C_2H_4+3O_2\rightarrow\left(t^o\right)2CO_2+2H_2O\\ n_{CO_2}=2.n_{C_2H_4}=2.0,5=1\left(mol\right)\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\\ n_{CaCO_3}=n_{CO_2}=1\left(mol\right)\\ m_{kết.tủa}=m_{CaCO_3}=100.1=100\left(g\right)\\ n_{O_2}=3.n_{C_2H_4}=3.0,5=1,5\left(mol\right)\\ V_{kk}=\dfrac{100}{20}.V_{O_2\left(đktc\right)}=5.\left(1,5.22,4\right)=168\left(lít\right)\)

$a\big)$

$n_{C_2H_5OH}=\frac{18,4}{46}=0,4(mol)$

$C_2H_5OH+3O_2\xrightarrow{t^o}2CO_2+3H_2O$

Theo PT: $n_{O_2}=3n_{C_2H_5OH}=1,2(mol)$

$\to V_{kk}=1,2.5.22,4=134,4(l)$

$b\big)$

$CO_2+Ca(OH)_2\to CaCO_3\downarrow+H_2O$

Theo PT: $n_{CaCO_3}=n_{CO_2}=2n_{C_2H_5OH}=0,8(mol)$

$\to m_{\downarrow}=m_{CaCO_3}=0,8.100=80(g)$

\(n_{CO_2}=\dfrac{4,48}{22,4}=0,2mol\)

\(C_2H_5OH+3O_2\underrightarrow{t^o}2CO_2+3H_2O\)

0,2               0,6       0,4         0,6

a)\(m_{C_2H_5OH}=0,2\cdot46=9,2g\)

b)\(V_{O_2}=0,6\cdot22,4=13,44l\)

\(\Rightarrow V_{kk}=5V_{O_2}=5\cdot13,44=67,2l\)

\(M_X=\dfrac{1.5}{\dfrac{1.775}{71}}=60\left(g\text{/}mol\right)\)

\(n_X=\dfrac{2.25}{60}=0.0375\left(mol\right)\)

CT : \(C_xH_yO_z\)

\(n_{CaCO_3}=n_{CO_2}=\dfrac{11.25}{100}=0.1125\left(mol\right)\)

\(\Rightarrow n_C=0.1125\left(mol\right)\)

\(m_{bt}=m_{CO_2}+m_{H_2O}=7.65\left(g\right)\)

\(\Rightarrow n_{H_2O}=\dfrac{7.65-0.1125\cdot44}{18}=0.15\left(mol\right)\)

\(\Rightarrow n_H=0.15\cdot2=0.3\left(mol\right)\)

Ta có : 

\(x=\dfrac{n_C}{n_X}=\dfrac{0.1125}{0.0375}=3\)

\(y=\dfrac{n_H}{n_X}=\dfrac{0.3}{0.0375}=8\)

\(M=12\cdot3+8+16z=60\left(g\text{/}mol\right)\)

\(\Rightarrow z=1\)

\(CT:C_3H_8O\)